I like software that does it by having "advanced [subset] options". That is, you have Options, with tabs A-F, each of which shows maybe 5 options, and at the bottom of each of those options, you can expand the remaining options for that tab.

(As opposed to having tabs A-F plus tab G for all the advanced options, I mean.)

Then, you can still find that option in the right place if you're looking for it, but you also aren't overwhelmed by too many choices.